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| موضوع: كتاب Petroleum Refining 4 - Materials and Equipment السبت 01 أغسطس 2020, 12:55 am | |
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أخوانى فى الله أحضرت لكم كتاب Petroleum Refining 4 - Materials and Equipment Edited by Pierre Leprince lnstitut Franqais du Petrole
و المحتوى كما يلي :
Foreword IX Nomenclature XXI PART ONE Separation Technologies Chapter 1 Gas-Liquid Contactors for Distillation: Plate Columns 1.1 General Characteristics of a Plate 1.1.1 Handling Liquid and Vapor Streams 1.1.2 Hydraulic Behavior of a Plate. Operating Zones 1.2 Types of Plates or Trays 1.2.1 Bubble Cap Plate 1.2.2 Sieve Plate with Downcomer 1.2.3 Valve Plate 1.2.4 Plates without Downcomers 1.2.5 Comparison of Plate Technologies 1.3 Correlations for Plate Sizing 1.3.1 Flooding Due to the Gas Phase. Choosing the Column Diameter 1.3.2 Determining Plate Spacing 1.3.3 Nature of the Gas-Liquid Mixture on the Active Zone.. 1.3.4 Downcomer Cross-Section 22XII CONTENTS 1.3.5 Weirs. Downcomers 1.3.6 Liquid Gradient on the Plate 1.3.7 Vapor Pressure Drop 1.3.8 Entrainment 1.3.9 Weeping 1.3.10 Efficiency 1.4 Calculating Plate Dimensions 1.5 Other Parts of a Column 1.6 Comparison of Different Types of Plates 40 References 40 Chapter 2 Gas-Liquid Contactors for Distillation: Packed Columns 2.1 Different Types of Packing... 43 2.1.1 Random Pacldngs ... 2.1.2 Structured Packings 2.1.3 Grids 2.2 Fluid Flow in Packings 51 2.2.1 Pressure Drop 2.2.2 Capacity .... 2.2.3 Hold Up 2.2.4 Minimum Liquid Irrigation Flow Rate 2.3 Packing Efficiency 2.3.1 Estimating HETPs 2.3.2 Estimating HTUs 2.4 Phase Distribution 2.5 Calculating a Packed Column 72 2.5.1 Principle of the Method 2.5.2 Example of Sizing a Packed Column 2.6 Packing or Plates? References Chapter 3 Solvent Extraction Equipment 3.1 General Hydrodynamic Features of Liquid-Liquid Systems 81CONTENTS XIII 3.2 Different Types of Extractors 3.2.1 Extractors without Outside Energy Contribution 3.2.2 Extractors with Outside Energy Contribution 3.3 Conclusion References 103 Chapter 4 Techniques for Physical Separation of Phases 4.1 Separation of Two Fluid Phases... 4.1.1 Gas-Liquid Separation 4.1.2 Liquid-Liquid Separation 4.2 Gas-Solid Separation 4.2.1 Cyclones 4.3 Liquid-Solid Separation 4.3.1 Filtration 4.3.2 Separation Using Centrifugal Force 4.4 Conclusion References 155 PART TWO Heat Transfer Technologies Chapter 5 Process Furnaces 5.1 Furnace Functions 159 5.2 Description of a Furnace.... 160 5.3 Different Types of Furnaces 5.4 Furnace Thermal Efficiency 5.5 Component Parts of a Furnace 5.5.1 Tube Bundles 5.5.2 Tube Coil Supports 5.5.3 Furnace Wall Lining .... 5.5.4 Burners 5.5.5 Air Heater 5.5.6 Sweepers 183XIV CONTENTS 5.6 Designing a Furnace 5.6.1 Determining Heat Exchange Surfaces 5.6.2 Fluid Dynamics in a Furnace 5.6.3 Mechanical Design of Structures 5.6.4 Control of Operating Furnaces References 222 Chapter 6 Heat Exchangers Introduction 223 6.1 Heat Exchanger Functions 6.1.1 The Cooling Function 6.1.2 The Heating Function 6.1.3 The Condensation Function. 6.1.4 The Vaporization Function 6.2 Operating Principle 6.2.1 Surface Exchangers 6.2.2 Direct Contact Heat Exchangers (or Mixing Heat Exchangers) 6.3 Technological Construction Principles and Circulation Modes... 6.3.1 Cocurrent (or Parallel Currents) and Counter-Current Circulation 6.3.2 Circulation Associating Cocurrent and Counter-Current 229 6.3.3 Cross-Flow Circulation 6.4 Parameters Influencing Exchanger Performance 232 6.4.1 Quality of Local Transfer 6.4.2 Circulation Modes 233 253 6.5 Critical Points in Selecting Heat Exchanger Type and Technological Design 6.5.1 Operating Conditions 6.5.2 Mechanical Resistance Conditions 6.5.3 Maintenance Conditions 6.5.4 Reliability in Performance and Mechanical Resistance.. 6.5.5 Economic Requirements 6.5.6 Availability of Calculation Methods to Predict Performance 6.6 Shell-and-Tube Exchangers...... 268 6.6.1 Types of Construction 6.6.2 The Shell 269 290CONTENTS XV 6.6.3 The Tube Bundle 6.6.4 Materials 6.6.5 Tube-Side and Shell-Side Circulation Circuits 6.6.6 Cost Estimation.. 6.7 Other Tubular Exchangers 6.7.1 Double Pipe or Coaxial Exchangers. Multi-Hairpin Exchangers 6.7.2 Heaters 6.7.3 In-Line Exchangers 6.7.4 Bayonet Exchangers 6.7.5 Helical Wound Coil Tube Heat Exchangers 6.8 Compact Non-Tubular Exchangers 6.8.1 Plate and Frame Exchangers 6.8.2 Brazed Plate Exchangers 6.8.3 Welded Plate Exchangers 6.8.4 Plate-Fin Exchangers 6.8.5 Printed Circuit Heat Exchangers (PCHE) 6.8.6 Circular Plate Exchangers 6.8.7 Spiral Plate Exchangers 6.9 Air-Cooled Exchangers 6.9.1 The Tube Bundles 6.9.2 Ventilation Systems 6.9.3 Plenum Chambers between Fans and Bundles 6.9.4 Structures 6.9.5 Air Cooled Exchanger Layout and Installation 6.9.6 Special Devices 6.9.7 Estimating Costs 6.9.8 Uses 6.10 Direct Contact Exchangers 375 6.10.1 Gas Coolers 6.10.2 Condensers 6.11 Conclusion 378 Appendixes 379 A6.1 Conversion Table 379 A6.2 Thermal Conductivity of Materials .. 380 A6.3 Characteristics of Exchanger Tubes A6.4 Heat Exchanger Types References 387XVI CONTENTS PART THREE Reaction Technologies Chapter 7 Chemical Reactor Technology 7.1 An Introduction to Reactors 7.1.1 Reactor Classification 7.1.2 Homogeneous Reactors 7.1.3 Reactors with Two Fluid Phases 7.1.4 Heterogeneous Catalytic Reactors 7.2 Reactors Used in Refineries 7.2.1 Steam Cracking 7.2.2 Dimerization 7.2.3 Gas Scrubbing by Chemical Absorption 7.2.4 Aliphatic Alkylation 7.2.5 Hydrogen Production 7.2.6 Catalytic Reforming 7.2.7 Catalytic Cracking 7.2.8 Hydrotreating 7.3 Conclusion References PART FOUR Mechanical Operations Chapter 8 Pumps, Compressors, Turbines, and Ejectors 8.1 Pumps 491 8.1.1 Centrifugal Pumps 493 8.1.2 Positive Displacement Pumps 514 8.2 Compressors 518 8.2.1 Reciprocating Piston Compressors 8.2.2 Centrifugal Compressors 8.3 Turbines 8.3.1 Steam Turbines 8.3.2 Gas Turbines 8.4 Ejectors 558 8.4.1 Operating Range 561 8.4.2 Sizing an Ejector 561 References 563CONTENTS XVII Chapter 9 Agitation and Mixing Techniques 9.1 The Medium 565 9.1.1 One-Phase Media: Liquid Alone 9.1.2 Media with Two Fluid Phases ... 9.1.3 Fluid + Solid Media 9.2 Agitation Systems 568 9.2.1 Different Types of Rotating Agitators 9.2.2 Static Mixers 9.3 Hydrodynamic Characteristics of the System 575 9.3.1 Hydrodynamic Regimes 9.3.2 Energy Dissipated by an Agitator.. 9.3.3 Mixing Time 9.3.4 Agitator Radius of Action 9.3.5 Velocity Gradient 9.3.6 Heat Transfer in Agitated Tanks 9.3.7 Mass Transfer in Agitated Tanks 9.4 Selecting an Agitation System 9.4.1 The Tank 9.4.2 Rotating Agitators 9.4.3 Other Mixing Techniques 9.5 Scaling-up . 9.5.1 General Relations 9.5.2 Power Input 9.5.3 Specific Problems 9.6 Prospects Nomenclature 575 576 579 583 584 585 587 589 589 591 596 600 600 604 604 609 609 References 611 PART FIVE Control and Optimization Techniques Chapter 10 Control and Monitoring 10.1 Introduction 617 10.2 Basic Principles of Industrial Measurements 617 10.2.1 Pressure 10.2.2 Flow Rate 619 621XVIII CONTENTS 10.2.3 Level 10.2.4 Temperature.. 10.2.5 Miscellaneous 624 626 627 10.3 Industrial Instrumentation Equipment 10.3.1 Sensors 10.3.2 Remote Transmission 10.3.3 Control Valves 10.3.4 Industrial Controllers 628 628 639 643 649 10.4 Analyzers 10.4.1 Simple Composition Analyzers 10.4.2 Mixture Composition Analyzers 10.4.3 Analyzers of Physical Characteristics 10.4.4 Gas Detection Analyzers 10.4.5 Analyzer Installation 10.4.6 On-line Analyzer Applications 10.5 Industrial Control 10.5.1 Level 10.5.2 Pressure 10.5.3 Flow Rate 10.5.4 Conclusion 10.6 Control Loop Design and Application 667 10.6.1 Closed Loops 10.6.2 Cascade Loops 10.6.3 Open Loops 10.6.4 Discontinuous Loops 10.6.5 Multi-Variable Loops 10.7 Process Automation 10.7.1 The Refinery and Automated Production 10.7.2 Automation Prerequisites 10.7.3 Operational Guidelines 10.7.4 Development Stages in an Automation Project 10.7.5 Control and Operating System 10.8 Centralized Control and Operation 10.8.1 Introduction 10.8.2 Systems and Architectures 10.8.3 Communications 10.8.4 Operating Interfaces 10.8.5 Processing Interfaces 680CONTENTS XIX 10.8.6 Programmable Logic Controllers (PLCs) 682 10.8.7 Safety PLCs 10.8.8 Associated Systems 10.9 Refining Operations in the Future References Chapter 11 Rational Use of Energy 11.1 Introduction 693 11.2 Energy Accounting 693 11.3 Energy Performance 11.3.1 Exergy 11.3.2 The Utilization Value of Energy Carriers 11.3.3 Exergy Analysis of an Industrial Process 11.4 Methods 11.4.1 Introduction 11.4.2 Distillation 11.4.3 Heat Exchangers Networks 11.4.4 Economic Optimization of a Heat Exchanger References 734 Index 735Catalytic cracking, 123, 137, 466-475 Cavitation, 500, 649 Centrifugal force, 101, 124, 148, 493 Centrifuge, 149 Change of phase, 233, 239 Chemical reactions, 389, 398, 429, 438, 442, 443, 444, 454, 456, 459, 466, 476, 566 Chimney, 478 Chromatograph, 658 Circulation, 253, 302, 351, 360, 474, 573 cocurrent, 227, 259, 369, 422 counter-current, 227, 259, 427 on a plate, 7, 8, 27 Coalescence, 83, 114 Coefficient convection, 196-198, 233-244 film, 233, 251 flow rate, 647 heat transfer, 225, 242, 249, 585 mass transfer, 33, 61, 65, 398, 588 Coil, 164, 315, 586 Coke, 430, 472 Collector, 354-356 Column baffle, 88, 375 distillation, 3-80 extraction, 85-91 packed, 43-77, 90, 376, 402, 443 plate, 3-40, 88, 402, 443 pulsed, 97 reciprocating plate, 101 rotating disk, 94 spray, 85, 375 tray, 7-89, 376, 402 with agitated compartments, 93-97 Absorptivity, 186, 190 Acid hydrofluoric, 444, 450-452 sulfuric, 444, 446450 Ae**ation factor, 6, 21, 29 FCC, 471 Air cooled condenser, 371 Air cooled exchanger, 224, 349-374 Alkylation, 93, 397, 444 Amine scrubbing, 397, 440 Amines, 20, 396, 442 Anchor, 570, 579, 581, 593 APi, 119, 366, 506, 510, 512, 554 Approach (temperature), 253-259, 721 ASTM, 661 Atomization, 176 Attrition, 137, 153, 466, 472 Automation, 671 Backmixing, 84, 402 Baffle, 237, 275, 295, 299, 590 Balance (thermal), 184, 253, 474, 696, 705 Bayonet, 319 Bearing (of compressor), 542 Blade (of turbine), 549, 554 Blowing, 11, 147, 183 Burners, 162, 175 Cake, 141 Capacity, 17, 54, 77, 100, 103, 433, 492 Carbon monoxide, 178, 456 Catalyst, 404, 454, 468-475736 INDEX Combustion, 175, 184, 559 Compression, 525, 530 Compressor centrifugal, 518, 530 reciprocating piston, 518, 520 Condensation, 106, 224, 241, 376, 545 Condenser, 224, 347, 376 Conduction, 198, 245 Conductivity (thermal), 174, 198, 239, 246, 380, 656 Distributor, 68-72, 473, 481 Downcomer, 4, 22-26, 89 Draft (of a furnace), 176, 219 Draw-off , 39 Drum, 111 reflux, 106 separator, 109, 116 Economizer, 224 Efficiency of centrifuge, 152 of column, 31, 60, 100 of compressor, 526, 534 of cyclones, 128 of furnace, 171, 185, 708 of packing, 60 of plate, 31, 36, 90 of pump, 495 of turbine, 546 Ejector, 558 Emissivity, 189-195, 203 Emulsion, 21, 112, 449 Energy electric, 695 heat, 184, 695, 701, 707 kinetic, 301, 532 Enthalpy, 216, 546, 551, 696, 705 Entrainment, 11, 18, 30, 108 Equilibrium (thermodynamic), 410 Erosion, 137, 265 Ethylene, 159, 429 Evaporator, 225 Exchange (heat), 157, 184, 233, 716, 731 Exergy, 704 Exergy analysis, 710 Expansion, 420, 428 Explosivity limits, 662 Extended surface, 252 Extraction solvent, 81 turbine, 549 Extractor (centrifuge), 101 Factor angle, 187, 195, 204 compressibility, 527 exchange, 187, 201 packing, 48, 56 power, 577, 581 SF, 20 Fan, 221, 361 FCC (see Catalytic cracking) Feed (inlet), 38, 470 Filter, 143-148 Filtration, 139 Contactor gas-liquid, 3, 43 liquid-liquid, 84, 403, 447 Control of a compressor, 529, 537 of a furnace, 221 of a turbine, 552 Controller, 649, 665, 682 Control loop, 665-671 Convection, 233-240 forced, 196 natural, 196 section, 165, 213 Conversion, 440, 456, 474 Cooler, 224, 475 Cooling, 224 Corrosion, 172, 265, 304 Cost, 17, 511, 693, 701 of air cooled exchangers, 373 of heat exchangers, 267-305 Cross-flow, 231, 260 Cyclone gas-solid, 122-139 liquid-solid, 153 Deasphalting, 93 Degassing, 7 Detection (of gas), 661 Dewaxing, 146 Diameter column , 4, 20 droplet, 83, 87, 112, 1IS, 448, 598 drum, 106-111 particle, 113, 124, 137, 152, 416, 424, 428 pump impeller, 499 tube, 172, 291, 309, 381, 433 Diffusivity, 65, 398, 407, 445, 588 Dimerization, 394, 438 Dipleg, 135, 468 Direct contact, 226, 375 Distillation, 34, 714, 730 vacuum , 53, 562 Distribution (phase), 66-72, 477 Distribution headers, 354 Distribution plate, 299, 359, 478INDEX 737 Fin (of exchanger), 198, 248, 310, 317, 337, ' 350-355, 374 Hold-up, 58, 82, 102, 321, 400, 402, 424, 428, 485, 588 HTU, 61-65 Humidification , 371 Hydrocracking, 476 Hydrocyclone, 153 Hydrodesulfurization, 476, 531 Hydrogen, 452, 476 sulfide, 440, 443 Hydrotreating, 476, 531, 718 Impellers of compressor, 534, 537 of pump, 497 Impingement plates, 301 Induced/forced draft, 232, 351, 368 Injector, 450, 467, 470 Interface, 115, 399, 444, 446, 679 Interfacial area, 33, 61, 65, 82, 399, 401, 444- 446, 567, 587, 598 Interfacia! tension, 19, 31, 59, 87, 90, 598 Flame, 175 Floating head , 269, 285 Flooding, 10, 18, 35, 55, 75, 90, 95 Flow laminar, 196, 233, 577 radial, 8, 462 solid, 133, 412, 465 turbulent, 197, 233, 577 two-phase, 197, 421, 476, 480 Flow meter, 621, 631 Flue gases, 160, 173, 184, 220 Fluidization gas-solid, 414, 469 liquid-solid, 414 three-phase, 414, 427 Foamability, 22 Fouling, 171, 248, 264 Fraction (of void), 48, 50, 53, 408 Front end stationary head, 269-283, 383 Fuel, 175, 558, 697, 701, 710 Furnace, 159-170, 435, 455 Kettle, 280 Lining (furnace wall), 174 Liquid gradient (on plate), 10, 26 Louvers, 363 Lube oils, 91, 146 Gravity, 112, 239 Grid , 64, 550 Head floating, 285, 383 rear, 283, 312, 383 type of, 269-290, 383 Materials for packing, 44, 60 for pumps, 511 for tubes, 173, 302-307, 321, 380 Mean (temperature difference), 254-260, 731 Measurement, 617 flow rate, 621 level, 624 pressure, 619 temperature, 626 Mixer, 85, 565-609 in-line, 571, 596 settler, 92, 404 tank, 589, 599 MTBE, 427 Heat latent, 184 specific, 197, 234, 239, 527 value, 177, 184, 701 Heater, 179, 224, 315 Heat exchanger cocurrent, 228, 253 compact, 323, 331 counter-current, 228, 256, 325 cross-current, 232, 260, 283 direct contact, 226, 375 double-pipe, 305-309 helical wound, 321 in-line, 319 lamella, 228 multi-hairpin, 305-311 Packinox, 333 plate, 228, 324, 328, 345 plate-fin, 335-342 printed circuit, 343 shell-and-tube, 228, 268, 384 spiral plate, 346 Heat flux, 204-212 HETP, 62-64, 91 Newtonian, 566 Nitrogen oxides, 178 NPSH, 499 Number Archimedes, 419, 42S Eotvos, 87, 90 Froude, 65, 429, 576, 602, 608 Galileo, 56 Hatta, 398, 445 Newton , 576738 INDEX Nusselt, 234, 585 of passes, 24, 27, 230 of plates, 33, 60 Peclet, 234, 407, 426 Prandtl, 196, 233, 585 Reynolds, 65, S9, 196, 233, 395, 419, 425, 428, 575, 585, 598, 602 Schmidt, 65 Stanton, 233 Weber, 65, 87, 425, 429, 598 Octane number, 460, 661 On-line analyzer, 654-664 Operating interface, 679 Optimization, 714 of exchangers, 731 Orifice, 16, 28, 87, 623 Oxidation, 173 Quench, 437 Racks. 317, 680 Radiation, 185, 200 Radiation section, 165, 200, 436 Radius of action (of an agitator), 583 Range (operating), 11, 492, 561 Rate (of reaction), 152, 398, 442, 445 Ratio (of phases), 114 Reactor catalytic, 394, 405 continuous stirred tank, 392, 396, 438 ebullating bed, 414, 427, 482 fixed bed, 405, 421, 461, 476 fluid bed, 136, 414, 467 gas-liquid, 394, 400, 440 liquid-liquid, 394, 403, 446 moving bed , 411, 464, 480 tubular, 392, 395, 440 Reboiler, 280 Recirculation, 371, 397, 447, 599 Recycle, 476, 485, 531 Redistribution, 67, 73 Reflectivity, 186 Reflux, 39 Reforming, 394, 460, 531 Regeneration, 472 Regenerator, 138, 468 Regime (flow), 196, 233, 239, 245, 423, 577 Residue, 239, 251, 474, 710 Resistance conduction, 226, 246 fouling, 226, 251 of cake, 141 Packing for distillation, 43-65, 75 grid, 47-50 random, 44-48, 91 structured, 47, 50 Phase dispersed, 83, 114, 567, 605 homogeneous, 395, 566, 604 liquid, 82, 438, 566, 604 Pinch, 719-730 Plate (of column), 440 Porosity, 142, 404 Power, 95, 495 of agitator, 95, 448, 576, 601, 603, 605 thermal, 184 Preheater, 224 Pressure (differential), 622 Pressure drop in a cyclone, 132 in a fixed bed, 408, 425 in a furnace, 214, 219 in a tube, 214, 235, 432, 455 in a valve, 648 of a plate, 9, 28, 35, 89 through an orifice, 28, 622 through packing, 51-54, 76 Process Clauspol, 443 Dimersol, 438 Programmable logic controller (PLC), 682 Propeller, 447, 569, 593 Protection plate, 301 Rings Intalox, 45 Lessing, 44 Pall, 45 Raschig, 44 Riser, 468, 470 Saddles Beri, 44, 48, 65, 91 Intalox, 45, 4S, 65, 443 Safety, 221, 637, 661, 689 Safety PLC, 685 Sampling, 654, 663 Seal, 213, 512, 540 Sealing strips, 278, 300 Section convection, 165, 213, 436 radiation, 165, 200, 436 Segmentation, 237 Selectivity, 405 Pump centrifugal, 145, 491 heat, 728 piston, 516 positive displacement, 145, 491, 514 rotary, 514INDEX 739 Sensor, 628 flow rate, 631 level, 634 pressure, 629 temperature, 634 Separation, 1, 105, 121, 139, 471 Settling, 113, 404 Shear, 240, 584, 602 Spacing (plate), 4, 20, 34, 89 Specific speed, 497 Spectrometer, 660 Stack, 162, 220 Standards, 510, 661 Standpipe, 471473 Steam cracking, 394, 429 Steam reforming, 453 Stripper, 468 Sulfur, 178 Superheater, 224 Supervision (centralized), 676, 689 Surface area exchange, 200, 213, 225, 254, 445, 587, 598, 729 specific, 47, 50, 54 Suspension, 139, 567, 607 Systems (control and supervision), 676, 689 Tray bubble, cap, 12, 17, 40 sieve, 12, 13, 17, 88, 99 valve, 12-14, 17 Trim (cooler), 224 Tube bundle, 162, 171, 199, 236, 288, 290, 359 corrugated , 238 expander, 294 furnace, 165, 171, 432, 455 heat exchanger, 238, 290, 308, 352, 381 sheet, 162, 269, 289, 292, 350 twisted, 238 Turbine agitation, 449, 569, 593 gas, 557 steam, 545 Two-phase flow cocurrent, 197, 240, 393, 423, 426, 480 counter-current, 43, 86-100, 393, 423, 483 Unburnt, 171, 178 Utilities, 698, 722 Value (of energy carriers), 706 Valve, 138 control, 643 Vapor blanketing, 243 Vaporization, 215, 225, 243 Vaporizer, 225, 321 Vapor pressure, 501 Velocity characteristic, 83 critical, 87, 108 minimum fluidization, 417, 428, 469 superficial, 400, 408, 424, 479 terminal falling, 118, 419 Vibrations, 266, 555, 627 Viscosity, 32, 113, 141, 196, 239, 443, 492, 503, 566, 593 Void fraction, 48, 408 Vortex, 126, 590 Tangential entrance, 122, 126, 153 Tank agitated, 92, 392, 573, 585, 589 settling, 118, 404 storage, 315, 591, 599 TEMA, 223, 268, 290, 301, 381 Thermal potential, 226, 254, 258 Time mixing, 579, 599, 601 residence, 22, 106, 120, 265, 395, 433, 468 Transfer by conduction, 198, 226 , 245, 249 by convection, 196, 226, 233, 249 heat, 185, 226, 249, 585 mass, 398, 443, 445, 587 Transmission analog, 639 digital , 640 Transmissivity, 186 Transport (pneumatic), 134 Wall, 168, 174, 246 Water, 118 Weeping, 11, 30 Weir, 6, 23
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