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| موضوع: كتاب Polymer Extrusion الجمعة 17 سبتمبر 2021, 3:23 pm | |
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أخواني في الله أحضرت لكم كتاب Polymer Extrusion Pierre G. Lafleur, Bruno Vergnes
و المحتوى كما يلي :
Table of Contents Introduction . ix Chapter 1. Continuum Mechanics, Rheology and Heat Transfer Overview 1 1.1. Continuum mechanics . 1 1.1.1. Strain . 1 1.1.2. Strain rate 2 1.1.3. Stress . 4 1.1.4. General equations in continuum mechanics 5 1.2. Rheology . 7 1.2.1. Newtonian behavior 7 1.2.2. General viscous behavior . 9 1.2.3. Effects on pressure and temperature . 10 1.3. Heat transfer [CAR 59, BIR 60, AGA 14] 11 1.3.1. The thermal balance equation . 11 1.3.2. Heat transfer during flow . 13 1.3.3. Cooling temperature 16 1.4. Bibliography . 19 Chapter 2. Calculation Methods . 21 2.1. Introduction 21 2.2. 1D solutions . 22 2.2.1. Isothermal calculation . 22 2.2.2. Non-isothermal calculations . 26 2.3. 2D solutions . 28 2.3.1. Network method (or FAN method) . 28 2.3.2. Finite element method . 32 2.4. Bibliography . 34vi Polymer Extrusion Chapter 3. Single-Screw Extrusion . 37 3.1. Introduction 37 3.2. Geometry and approximations . 39 3.3. Solid conveying zone 45 3.3.1. Phenomenological description 46 3.3.2. Modeling . 47 3.3.3. Synthesis . 63 3.3.4. Determination of physical parameters 65 3.4. Melting zone . 73 3.4.1. Phenomenological description 73 3.4.2. Modeling . 76 3.5. Metering zone 85 3.5.1. Phenomenological description 85 3.5.2. Modeling . 85 3.6. Overall model 95 3.7. Technological improvements . 99 3.7.1. Grooved barrels . 100 3.7.2. Barrier screws 102 3.7.3. Mixing heads 103 3.8. Conclusion 105 3.9. Bibliography . 105 Chapter 4. Co-rotating Twin-Screw Extrusion 109 4.1. Twin-screw extrusion 109 4.1.1. The different types of extruders . 109 4.1.2. Different flow types 111 4.2. General overview of co-rotating twin-screw extruders 113 4.2.1. Characteristic features of co-rotating twin-screw extruders . 113 4.2.2. Geometry of the screws and barrel 115 4.2.3. Conventional approximations . 119 4.3. Solid conveying zone 120 4.4. Melting zone . 121 4.4.1. Experimental studies 122 4.4.2. Theoretical models . 125 4.5. Flow in the molten state 128 4.5.1. Right- and left-handed screw element 128 4.5.2. Mixing elements 138 4.5.3. Heat transfer . 146 4.5.4. Residence time distribution 147 4.6. An overall model of twin-screw extrusion 151 4.6.1. General description . 151 4.6.2. Calculation algorithm . 154Table of Contents vii 4.6.3. Residence time distribution 155 4.6.4. Example of results using the LUDOVIC software 157 4.7. Compounding application and production of complex materials 162 4.7.1. Compounding and mixing . 162 4.7.2. Reactive extrusion . 170 4.7.3. Polymer blends . 177 4.7.4. Production of clay-based nanocomposites . 185 4.7.5. Optimization and scale-up . 194 4.8. Conclusion 198 4.9. Bibliography . 198 Chapter 5. Profile Extrusion . 211 5.1. Profile extrusion . 211 5.1.1. Different types of profile dies . 211 5.1.2. Flow calculation inside profile dies . 213 5.1.3. Evaluation of post-extrusion phenomena 214 5.1.4. Design of extrusion dies 221 5.2. Pipe extrusion 229 5.2.1. Introduction . 230 5.2.2. Flow calculation 230 5.3. Calibrators 240 5.3.1. Friction calibrators . 240 5.3.2. External compressed air calibrators . 240 5.3.3. External vacuum calibrators . 241 5.3.4. Internal calibrators . 241 5.4. Conclusion 241 5.5. Bibliography . 241 Chapter 6. Production of Films and Sheets 245 6.1. Introduction 245 6.2. Cast film extrusion . 249 6.2.1. Processing 249 6.2.2. Designing the flat die . 250 6.3. Film blowing . 256 6.3.1. Process overview 256 6.3.2. Film blowing models 267 6.3.3. Multilayer films . 292 6.4. Conclusion 298 6.5. Bibliography . 298viii Polymer Extrusion Chapter 7. Wire Coating and Cable Insulation 305 7.1. General process . 306 7.1.1. Production line . 306 7.1.2. Wire coating dies 307 7.2. Commonly encountered problems 310 7.3. Analyses and solutions . 310 7.3.1. Theoretical studies . 311 7.3.2. Experimental studies 330 7.4. Conclusion 330 7.5. Bibliography . 331 Index 33 Index A, B activation energies, 276, 296, 298 energy, 11, 31, 172, 232, 274, 276, 294, 296–298 adiabatic flow, 14–15 apparent density, 46, 69, 71 Arrhenius equation, 10, 31, 232, 238, 270, 274, 288 average residence time, 148–150, 155 temperature, 14–16, 26, 27, 146, 154, 214, 323, 324 barrel velocity, 44, 48, 49, 76, 94 barrier screws, 102–103 biot number, 322 blow-up ratio, 257, 292 breaks, 165 Brinkman number, 27 C C-chamber, 111, 120, 122, 128, 130, 133 Cameron number, 27 capillary number, 178, 179–181, 183 Carreau's law, 9, 22 Carreau-Yasuda law, 9, 172, 188 cast film extrusion, 249–255 centerline distance, 115–117 channel depth, 40–42, 53–55, 64, 80, 81, 115, 118 width, 41, 42, 87, 119, 120, 130, 152 characteristic curves, 87, 88, 132, 134, 135 value, 22, 25 coalescence, 178, 180–184 coat-hanger geometry, 249 coextrusion, 309 coextrusion die, 257, 259, 309 compaction zone, 46–47 compounding, 162–170 continuity equation, 5–6 controlled degradation, 170, 172, 176, 177 conversion rate, 172, 175, 195 cooling ring, 263, 264, 272, 273, 276, 277, 291, 295 co-rotating extruders, 112 counter-rotating, 12, 109–112, 236 cross-head die, 306, 307 crystallization, 264, 273, 274, 279, 298 cumulative strain, 165336 Polymer Extrusion D, E Deborah number, 278 delay zone, 38, 47, 59, 60, 66, 75 dimensioning of extrusion dies, 223– 229 dispersive mixing, 165–170 distribution channel, 250–254, 258, 259, 329 distributive mixing, 163–165 energy equation, 26, 57, 77, 78 transfer cables, 305 equilibrium equation, 6 erosion, 166, 167, 169, 177, 192 extrudate swell, 214–217 F, G, feed rate, 80, 114, 120, 121, 124, 173, 190, 196 zone, 40, 45–47, 49, 57, 66, 75, 114, 120, 121, 308, 310, 311, 329–330 filling ratio, 114, 121, 123, 150, 151, 159, 160 film blowing dies, 258–261 flat die, 250–255, 310, 329 flexible packaging, 245, 246, 248 flight thickness, 116, 117 flow balancing, 226–227 rate of the solid, 49–53 force of interaction, 324–325 friction coefficient, 65–69 functional zones, 38, 40, 95, 113, 120 H, I, K heat flux, 12, 16, 17, 57, 77, 78 transfer coefficient, 12, 16–18, 126, 146, 147, 154, 158, 271, 273, 279 transfer, 11–19, 146–147 hydrostatic pressure, 5, 45, 63 independent channels, 118 instability problems, 264–266 interface temperature, 19, 47 interpenetration zone, 111, 112, 116, 118–120, 131, 141 kneading elements, 113, 114 L, M, N lateral pressure coefficients, 72–73 longitudinal flow, 86–88 lubrication approximation, 139, 141, 231, 237, 262, 318, 320, 325, 328 mean temperature, 231–233, 238, 239, 288 melting model, 76, 125, 152, 196 rate, 78, 79 zone, 73–84, 121–127 metering zone, 85–94 mixing heads, 103–105 indices, 163 nanocomposites, 162, 185–193 network method, 28–32 model, 29, 213, 223, 224, 229 Newtonian behavior, 7–8 fluid, 76–82 number of flights, 115, 117, 118, 119 Nüsselt number, 16, 146, 158, 159, 232 O, P, R optimization, 194–197 overall model, 95–99 penetration depth, 18 pitch angle, 41 planar shear flow, 3 Poiseuille flow, 3 polymer blends, 177–185Index 337 power dissipated, 11–13, 16, 126, 154 law, 9 law fluid, 12, 22, 25, 30, 31, 60, 82, 85, 90, 91, 156, 214, 227, 252, 253, 261, 262, 317 pressure field, 136, 137, 142, 143, 144, 145, 163, 164, 214, 253 flow, 316–318 profile, 58–60, 63, 82, 98, 139, 140, 160, 161, 314, 324 temperature fields, 238 profile dies, 211–214, 224 pulling force, 269, 288 reactive extrusion, 170–177 residence time distribution, 147–151 restrictive elements, 114, 158, 159, 197 right-and left-handed screw element, 128–137 S scale-up criteria, 99 screw body diameter, 41 cross-section, 115 diameter, 42, 115, 117, 120, 146, 147 elements, 113–115, 121, 123, 125, 129, 136, 138, 144, 150, 152 screw-barrel system, 38, 41, 105 shape factors, 90, 132, 152 shear flow, 315–316 flow rate, 129, 130, 132, 316 shrinkage, 217 single-screw extruder, 37, 65, 73, 95, 99, 103, 109, 110, 112, 113 slab method, 27, 232, 319, 324 solid bed profile, 80, 82, 83 conveying zone, 45–73 specific energy, 99, 124, 152–154 mechanical energy (sme), 152 strain rate, 2–3 stress, 4–6 stretching, 217 T, V, W take-up ratio, 257 telephone wire, 305, 308, 329, 331 temperature profile, 233 thermal balance equation, 11–13 diffusivity, 14, 17, 232 effusivity, 19 time-temperature superposition, 10 transfer coefficient, 12, 16–18, 126, 146, 147, 154, 158, 217, 273, 279 transverse flow, 88–89 tubes, 19, 211, 284 twin-screw extrusion, 109–112 velocity profiles, 42, 62, 92, 133, 134, 227, 271, 277, 278 viscosity, 7 volumetric flow rate of the solid polymer, 49 Weissenberg number, 216, 217 wire coating dies, 307–309
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