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| موضوع: كتاب Metallocene Catalyzed Polymers - Materials, Properties, Processing and Markets الأحد 30 يوليو 2023, 3:19 am | |
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أخواني في الله أحضرت لكم كتاب Metallocene Catalyzed Polymers - Materials, Properties, Processing and Markets George Me Benedikt , Brian L Gooddl
و المحتوى كما يلي :
Table of contents Polyethylene Polypropylene Polystyrene Ethylene-Olefin Ethylene-Propylene-Diene (EPDM) Nonbornene Copolymers The Market Special Attributes Materials Economic Factors for the Production of Metallocene and Perfluorinated Boron Cocatalysts Polypropylene Reinvented Cost of Using Metallocene Catalysts New Approaches for Ziegler-Natta Catalysts for Polypropylene UNIPOL? Gas Phase Copolymerization with SSC Metallocene Technology High-Molecular-Weight Atactic Polypropylene from Metallocene Catalysts. Influence of Ligand Structure and Polymerization Conditions on Molecular Weight Homo- and Co-polymers Derived from Multicyclic Olefin Monomers: The Quest for Higher Tg Materials The Renaissance in Polyolefin Manufacturing Technology Mixed Metallocenes for Designer Polymers Advances in the Functionalized Polyolefins Synthesis and Applications SPS Crystalline Polymer: A New Metallocene-catalyzed Styrene Engineering Thermoplastic Ethylene/a-olefin Copolymers with Metallocene Catalysts in High Pressure Process Semicrystalline Polyolefins - Narrow MWD and Long Chain Branching: Best of Both Worlds Structure and Properties of Single Site Constrained Geometry Ethylene-Propylene-Diene, EPDM, Elastomers Enhancing Polyethylene Performance with INSITE? Technology and Molecular DesignProperties Morphological Investigation on Very Low Density Ethylene-Octene Metallocene Copolymers Using SAXS Further Studies on Metallocene ULDPE/PP Blends Impact-Morphology Relationships Morphology of Low to Very Low Density Ethylene-Octene Metallocene Copolymers Morphological Studies of Metallocene Plastomer Modified Polypropylenes Comparison of the Crystallization Behavior of Ziegler-Natta and Metallocene Catalyzed Isotactic Polypropylene Explaining the Transient Behaviors of Syndiotactic Polypropylene Equilibrium Melting Temperatures of Ethylene Copolymers: An Appraisal of the Applicability of the Flory and Sanchez-Eby Approaches Melt Rheology and Processability of Ethylene/Styrene Interpolymers Characterizing the Melt Relaxation Behavior of Metallocene Polyethylenes Studies on the Thermal Stability and Processability of Syndiotactic Polystyrene The Performance of Primary and Secondary Antioxidants in Polyolefins Produced with Metallocene Catalysts. Part 1. Preliminary Studies Comparing m-Syndiotactic and Isotactic Polypropylenes Metallocene Plastomer Modification of Clear Polypropylene for Impact Enhancement Frictional Behavior of Polyethylenes with Respect to Density and Melting Characteristics Crystallinity Dependence of Modulus and Yield Properties in PolyethylenesProcessing Processing Characteristics of Metallocene Propylene Homopolymers Performance - Property of Novel Glass Fiber Reinforced Polypropylene Compounds and Their Applications Injection Molding of Glass Fiber Reinforced Syndiotactic Polystyrene Injection Molding Optimization Procedures for Polyolefin Plastomers and Elastomers Potential Film Applications of Metallocene-based Propylene Polymers from Exxpol? Catalysis Effect of Various Polyethylene Structures on Film Extrusion An Innovative Approach to Understand Metallocene Based Polyolefins and Thermoplastic Resins for Film Applications Extrusion Behavior of Exxpol Metallocene Polypropylene The Effects of Long Chain Branching of the Processing-Structure-Property Behavior of Polyethylene Blown Film Resins Spherilene Process LLDPE for Conventionally Blown Shrink Film Blown Film Characterization of Metallocene Resins Made in the Phillips Slurry Loop Process Comparison of the Fiber-Spinning Properties of Ziegler-Natta and Metallocene Catalyzed Polypropylene Metallocene Linear Low Density Polyethylene Blends for Pouch Materials in High-Speed Hot-Liquid Filling Process Blends of SIS Block Copolymers with Ultralow Density Polyethylenes Preparation of Metallocene Plastomer Modified High Flow Thermoplastic OlefinsMarkets Metallocene Capabilities Drive Success of Innovative Packaging Manufacturer Impact of Technology on Global Polyethylene Technology Impact of Metallocene Based Polypropylene on Existing Polypropylene Technologies and Markets New Polyethylenes for Targeted Performance Based Applications Polyvinyl Chloride Replacement for Flexible Medical Tubing Index A abrasion resistance 374 acid neutralizer 20I activation energy 181 active coordination site 28 active site 36 adhesion 81, 86, 330, 332 aging 164,200 alloys 243 amorphous 163,225 amorphous region 123 ansa-zirconocene catalyst 22 antiblock agents 305 antioxidants 193,201 Arrhenius plot 47 aspect ratio 151 atactic 24, 43,50, 157, 193 autoignition temperature 248 automobile parts 193 automotive 93, 247 Avrami equation 141 B BASF 64 BFGoodrich 57 birefringence 318 blends 74, 85, 138, 328, 329, 348 block copolymers 85 bloom 166 blow molding 66,185,209 blown film 101, 185,278,291,299,305 blowup ratio 271 boiling point 182 borane moiety 87 boron-based cocatalysts 1 branch content 141 branching frequency 142 bridge length 29 bridging moiety 29 INDEX Brintzinger's catalyst 5 brittle failure 342 brittle matrix 138 brittle-ductile transition 138 bubble stability 271, 277 C cable jacketing 122,373 calcium stearate 201 Capillary number 154 carbon monoxide 63 catalyst activity 48 decay 36 residue 201 systems price ranges 14 return on investment 14 chain branching 271,291,369 length 106 transfer 108 transfer reaction 43 chain-end structure 38 chain-folding model 123 chemical resistance 89, 93 chemical shift 60 clarity 211, 305 cocatalyst 8 coefficient of friction 167 coextrusion 123 computer-aided design 121 constrained-geometry 6 cooling rate 250 copolymerization 32, 36, 57, 81, 99 copolymers 169, 179,216,329,339,369 Cox-Merz rule 114, 182 . Cross model 179 crosslinking 280 crossover frequency 180 crystal382 density 142 perfection 167 thickness 130, 142 crystalline domains 89 crystallinity 84,116,127,160,165,199, 231,280 crystallization 157, 315 D dart impact 102, 309, 371 deactivation 81 Deborah number 185 deflection temperature 91 degradation 178 density 64, 100, 135,217,223,300,305, 316,339,371 development cost 3 Dex Plastomers 67 Dexco 330 dielectric strength 92 dimensional stability 91, 247 discoloration 193 dispersed phase 335 dispersion 149 dissipation factor 92 DMA 137, 165,332 dominant defect 142 Dow 21,64,66, 103, 127, 141, 171, 177, 330,369 drawdown ratio 271 DSC 79, 114, 130, 136, 141, 158, 194,217, 249,279 DSM66 ductility index 341 dyeability 81 E electrical housing 193 electrical properties 89 electron-donating groups 28 Elf Atochem 64 elongation 374 Metallocene-catalyzed Polymers enantioface 24 enchainments 58 endotherm peak 325 energy consumption 271 Eni~hem 64, 331 entanglement 167 enthalpy of melting 159 EPDM 71,113,359 ethylene 77 ethylene/a-olefin copolymer 97 ethylene-propylene copolymer 12, 359 EVA 65,100,281,348,354,374 EVAc 323 extensional flow 232 extensional viscosity 277 extraction 84 extruder 156, 185,215,231,240,316,324, 339 extrusion 200,202,233,271,283 Exxon 21,66,73,231,261,283,330 F ferrocene 1 fiber 236 fiber spinning 231 fibers 315, 363 fibrils 139 filaments 316, 363 film 236,262,271 film applications 123 film blowing 271, 277, 291 film casting 231 Fina 21, 163, 199,359 flexural modulus 123,225 Flory equation 169 F1ory-Vrij equation 169 flow direction 250 fractionation 84, 100, 158 free radical polymerization 64 friction 219 frictional stress 224 fringed micellar crystals 127Index frost-line height 271 FTIR 114, 157, 158 functional cost analysis 2, 4 G Gardner impact 91, 241 gas phase 63, 360 gas phase copolymerization 35,37,39,41 Gibbs-Thomson equation 146 glass fibers 239, 247 glass reinforced 89 glass transition temperature 57, 61,114,135 GPe 53, 194,294 graft copolymers 85 383 impact energy 213 impact strength 91, -292 injection molding 123,240,247,253 injection pressure 94, 256 injection time 254 insoluble fraction 59 interface 139 interfacial tension 149 interfacial thickness 129 intrinsic viscosity 100 ionomer resins 278, 354 irradiation 277 isotactic 27,57, 79, 84, 157, 163,200,203, 315,359 H hardness 256, 329, 333 haze 212,263,311 HDPE 65,66,188,271,278,292 heat deflection temperature 240 heat of fusion 142, 250, 283 heat resistance 90, 247, 325 heat seal temperature 100, 305 heat sealing 163 heat shrink film 277 heat-sealable material 323 hemi-isotactic structure 25 heteronuclear correlation 61 high pressure 63 Hoechst 71,261 Hoffman-Weeks method 159 Hoffman-Weeks plot 141, 169 hydride elimination 40 hydrogen 77 hydrophilic functional groups 85 hydrophobic 86 hydrotalcite 206 hydrotrimers 60 I Idemitsu 193 image analysis 150 L labor cost 6 lamellae 123, 142, 161 lamellar thickness 101, 171 LDPE 11,271,278,299,323,353 Lewis acid 81, 103 lids 125 life-cycle 2 ligand structure 37,97 ligands 1 liquid crystal polyester 91 LLDPE 11,21,40,66,97; 102, 105, 121, 145,186,216,271,292,299,323,352,369 long chain branching 39, 57, 103 loss modulus 119,271 M market sectors 354 Mark-Houwink-Sakurada parameter 52 medical applications 213 melt 177 melt elasticity 286 melt flow rate 99, 149,201,212 melt fracture 294,371 melt index 37, 64, 69, 200, 279, 339 melt strength 119, 177 melt viscosity measurements of several384 polymers 93 melting behavior 141 melting index 196 melting point 27, 28, 90,101,159,169,193, 280,283 metallocene capital investment 11 comparison 7 cost contributions 7 cost of use 11 isospecific 24 manufacturing 4 manufacturing cost 13 moisture sensitivity 2 molecules 1 prices 9 production cost 1 purit-y 74 yield 4 methylaluminoxane 11 microstructure 84,116,121,315 microtacticity 79 Mitsubisll.i Petrochemical 64 Mitsui Petrochemical 66 mixing 339 mobility 118 moisture sensitivity 89 mold flow 94 moldability 105 molecular design 121, 122 molecular motion 180 molecular movement 163 molecular weight 37, 43,57, 73, 103, 128, 158,169,171,178,231,253,271,283,305 monomer concentration 44 monomer pressure 99 Monte Carlo simulation 103 Mooney viscosity 114 morphology 31, 85, 127, 135, 185,225,268 multicyclic monomer 57 MetaUocene-catalyzed Polymers N Newtonian fluid 155 Newtonian plateau 232 Nippon Oil 70 ~47,53,59,83, 158,293 norbomene 57 Nova 66 nucleating agents 209, 315 nucleation 199, 318 o orientation 235,315 oxidation 193 p packaging 345 paintability 81 particle size 138, 149, 151 patents 21 Phillips 67, 103,227,291,305 phosphites 202 pilot plant 3, 100 pinhole 302 platelet-like structure 146 PMMA85 Poisson's ratio 225 poly- phenylene sulfide 91 polycycloolefins 359 polydispersity 37, 104, 128, 141 polyethylene 21, 37, 57, 64,82,121,139, 179,185,211,215,225,271,277,291,305, 329,346,353,359 polyethylene terephthalate 209,323 polyethylenes 11, 169 polymer backbone 81 polymer segment 85 polymerization 52 polymerization temperature 43,47, 51 polyolefins 4,63,81, 103,240,253,277, 305,351,359 polyphthalamide 91 polypropylene 11, 18,21,22,43,57,83,Index 138,149,157,163,199,209,231,239,262, 283,315,339,359 polypropylenes 157 polystyrene 57, 89, 179, 193,247 Porod Law 130 Porod region 129 pouch 323 printability 81 processability 89, 105 propagation 108 propagation rate 43 propylene-ethylene copolymer 50 puncture resistance 334 purification steps 4 PVC 253 R random copolymers 32 reactive groups 81 reactivity 99 reactor impurities 74 recycling 289 reinforcement 239 relaxation time 185 reptation 185 Rexene 64 rheology 177,186,281,291 S Sanchez-Ebyequation 169 SANS 149 SAXS 127, 142, 171 sealant 124 sealing 371 SEM 86,136, 149 semicrystalline 225, 255 shear strength 218 shear thinning 104 shear zone 250 Shell 71,330 short chain branching 64, 135 shot size 256 385 shrinkage 241, 263, 299 shrink film 299 side reactions 81 silica support 12 single site catalyst 11,63 slurry loop process 63, 305, 360 solution phase 63 specific gravity 93 spherulites 101, 127, 142,204 spinneret 234 stereochemical sequence 60 stereoisomers 60 stereoregularity 157, 199 stereorigidity 98 stereospecific polymerization 23 steric barrier 106 stiffness 209, 225, 236, 263 storage modulus 119,271 stress relaxation 186 surface tack 329 syndiotactic 22, 47,57, 163, 193, 199,203, 247,359 T tacticity 30, 61, 261 Taylor's equation 154 tear strength 104, 292, 305, 332, 333 tensile modulus 91 tensile strength 92, 102, 116,241,334,374 tennination 77 TGA 194,248 thennal expansion 251 thennal stability 178, 193 thickening 280 thickness 305 Thompson-Gibbs plot 169 Thompson-Gibbs relationship 169 tie chain 370 tie molecules 123 titanocene dichloride 1 torque 288 Tosoh 66386 toughness 305 U ULDPE 135, 374 uniaxial tension 142 Union Carbide 35, 70 V vanadium systems 23 vinyl unsaturation 105 visbreaking 232, 283 viscoelastic behavior 271 viscosity 152, 179, 231, 248, 277, 286 VLDPE65 volatiles 236, 305 w \vater absorption 92 WAXD 141 Wu's model 149 y yellowness index 201 yield point 142 Young's modulus 116, 225 Z Ziegler-Natta 21,38,64,81,103, 121, 135, 157,165,188,199,209,231,240,315,329, 360 zirconocene catalyst 58 zirconocene dichloride 1, 5 zirconocene system 11 MetaUocene-catalyzed Polymers
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