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| موضوع: كتاب Metallocene Technology in Commercial Applications الأحد 20 أغسطس 2023, 2:40 am | |
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أخواني في الله أحضرت لكم كتاب Metallocene Technology inCommercial Applications Dr. George M. Benedikt, Editor
و المحتوى كما يلي :
Table of Contents Preface vii George M. Benedikt Catalytic Systems Single-Site Supported Catalysts for Ethylene 1 A. MuÔoz-Escalona, L. Mendez, B. PeÔa, P. Lafuente, J Sancho, W. Michiels, G. Hidalgo and Ma. Fca. Martinez-NuÔez Synthesis of High-Molecular-Weight Elastomeric Polypropylene with Half-Titanocene/MAO Catalysts 9 Oing Wu, Benheng Xie, Meiran Xie, Rui Chen Precessing Methods Blending Is Metallocene Polyethylene Blend with HDPE More Compatible Than with PP? 17 D. Rana, K. Cho, B. H. Lee and S. Choe Spherulite Boundary Strengthening: A New Concept in Polymer Blends 23 A. Lustiger, CN. Marzinsky and R. R. Mueller Modification of Syndiotactic Polystyrene 29 JØrg Kressler, Ralf Thomann Blends of Ethylene/Styrene Interpolymers and Other Polymers: Benefits in Applications 37 C.F. Diehl, M. J. Guest, B. I. Chaudhary, Y. W. Cheung, W. R. Van Volkenburgh, B.W. Walther Extrusion Easy Processing Metallocene Polyethylene 47 Ching-Tai Lue Effect of Metallocene Polyethylene on Heat Sealing Properties of Low Density Polyethylene Blends 53 Juan D. Sierra, Mar˝a del Pilar Noriega and Tim A. Osswald Extrusion Operation Window for Filled Metallocene Polyethylenes 61 Mar˝a del Pilar Noriega and Tim A. Osswald, Omar A. Estrada Processing Trends of Metallocene Linear Low Density Polyethylenes and Their Influence on Single Screw Design 69K. R. Slusarz, C. A. Ronaghan, and J. P. Christiano Influence of mPE Grades on the Dynamic Properties of PP/mPE-Blends 77 Frank Raue and Gottfried W. Ehrenstein fiSingle-Site Catalyzed Polyolefin for Fresh-Cut Produce Packaging. A Comparison Between Monoextruded Blends and Coextruded Film 85 V. Patel, S. Mehta, S. A. Orroth and S. P. McCarthy Rheology and Processing Experience of New Metallocene Polyolefins 93 Atul Khare, Chuan Qin, Michael T. K. Ling, and L. Woo Film Forming Properties and Film Applications of Metallocene-Based Isotactic Polypropylenes 101 Aiko Hanyu and Rusty Wheat Phase Structure Characterization and Processing-Structure-Property Relationships in Linear Low-Density Polyethylene Blown Films 111 Jianjun Lu, Baiyi Zhao and Hung-Jue Sue The Relative Influences of Process and Resin Time-Scales on the MD Tear Strength of Polyethylene Blown Films 121 Rajendra K. Krishnaswamy and Ashish M. Sukhadia Metallocene Catalyzed Polyethylene in Blown Film Applications. A Comparison Between Monoextruded Blended Films and Coextruded Films 129 C. M. Beagan, G. M. Mc Nally & W. R. Murphy Trade-offs in Blown Film Processing-Structure-Property Behavior of LLDPE Type Resins from Chromium, Metallocene and Ziegler-Natta Catalysts 137 Ashish M. Sukhadia Injection Molding Transparent Metallocene-Polypropylene for Injection Molding 147 J. RØsch, J. R. Grasmeder Equipment Design Considerations for Processing with Metallocene Resins 153 Andrew W. Christie Other Processing Methods Product and Process Developments in the Nitrogen Autoclave Process for Polyolefin Foam Manufacture 157 D. E. Eaves and N. Witten Properties of Syndiotactic Polypropylene Fibers Produced from Melt Spinning 167 Mohan Gownder iv Metallocene TechnologyMelt Spinning of Syndiotactic Polypropylene: Structure Development and Implications for Oriented Crystallization 177 Ravi K. Sura, Prashant Desai and A.S. Abhiraman Properties New Polyolefins Characterization by Instrumental Analysis 183 Carmina Gartner and Juan D. Sierra, Roger Avakian Dynamic Melt Rheometry Used to Study Degradation of Metallocene Polyethylene 193 Scott H. Wasserman, George N. Foster, Douglas J. Yacka Melt Rheology and Processability of Conventional and Metallocene Polyethylenes 201 Choon K. Chai Rheology of Metallocene-Catalyzed Polyethylenes. The Effects of Branching 209 Sujan E. Bin Wadud and Donald G. Baird Extensional and Shear Rheology of Metallocene-Catalyzed Polyethylenes 217 Sujan E. Bin Wadud and Donald G. Baird A Criterion for the Onset of Gross Polyolefins: Molecular Structure Effect 223 Seungoh Kim and John. M. Dealy Relationship Between Structure and Rheology of Constrained Geometry Catalyzed and Metallocene Polyethylenes 231 Paula Wood-Adams and John M. Dealy The Influence of Sequence Length Distribution on the Linear Crystal Growth of Ethylene-Octene Copolymers 239 John E. Wagner, Samir Abu-Iqyas, Kenneth Monar and Paul J. Phillips Crystallization and Microstructure of Ziegler-Natta and Metallocene Based Isotactic Polypropylenes: Simulation and Experiment 247 Y. Churdpunt and A. I. Isayev Crystallization of Ethylene-Octene Copolymers at High Cooling Rates 257 Paul J. Phillips and John Wagner Kinetics of Non-Isothermal Crystallization Syndiotactic Polypropylene: Avrami, Ozawa, and Kissinger Approaches 263 Pitt Supaphol and Joseph E. Spruiell High Temperature Flexible Polyolefins a Users Perspective 275 Atul Khare, Samuel Y Ding, Michael T. K. Ling, and L. Woo Table of Contents vMarkets An Outlook for Metallocene and Single Site Catalyst Technology into the 21st Century 283 Kurt W. Swogger World Olefins Markets: Issues Influencing Availability and Pricing 293 Robin G. Harvan World Polypropylene Demand 299 Russ DeLuca PVC Markets, Today and in 2020 303 Donald Goodman Index 307 vi Metallocene TechnologyPrefac A ABS 293 activation energy 29, 97, 212, 271 agricultural films 137 amorphous 9, 23, 37, 112, 147 agent 130 appearance 67 atactic 9, 23, 29, 37, 187, 279 autoclaving 275 Avrami equation 249 kinetics 263 theory 157, 265 B bags 137 barrel 73 birefringence 178, 223 birefringent 148 blends 17, 27, 29, 38, 48, 53, 62, 77, 129, 164 blow molding 87, 117, 122 blowing agent 157 branches 5, 261 branching 193, 217, 232 brittleness 29 bubble 118, 122 stability 204 C can liners 137 capillary flow 223 cell structure 159 chain 13 chromium 1 clarity 47, 147 cobalt 1 coextrusion 129 compatibility 17 conductivity 165 conformation 167, 180, 279 contamination 275 cooling 247 copolymers 6, 31, 164, 194, 209, 258 distribution 77 copolymerization 10, 239 Cox-Merz rule 234 CP/MAS 178 critical stress 227 crosslinking 157, 193 crystalline 23 modifications 29 crystallinity 94, 107, 264 crystallites 105 crystallization 18, 54, 112, 117, 150, 177, 239, 257, 263 kinetics 168 cushioning 160 cyclic loading 78 D damping factor 78 debonding 38 defects 102 degradation 194 die 64, 224 diffusion 54, 159 DMS 178 Doi-Edwards model 233 driving force 13 IndexDSC 15, 26, 30, 55, 87, 103, 113, 130, 135, 170, 178, 183, 248, 252, 264, 266 dynamic modulus 82 E elastic recovery 172 elasticity 41 elongation 20, 132, 171 endotherm 106 EPDM 77, 279 EPR 279 equipment design 154 ethylene 1 ethylene/styrene interpolymer 37 EVA 53, 86, 94, 163, 278 exotherm 267, 272 expansion 157 extensional flow 224 viscosity 217 extractables 148 extruder 48, 61, 138, 154, 177 extrusion 17, 69, 86, 97, 170, 197, 201, 223 F fatigue 78 fiber 168, 177 film 17, 38, 69, 85, 111, 117, 122, 129, 168, 177, 201 flexural modulus 27 Flory equation 240, 258 foam 38, 157 fold surface 261 food 93, 137 free energy 261 fresh-cut produce 85 FTIR 183 microscopy 26 fusion 189 G gas permeability 47 gelation 150 GPC 6, 18, 236 growth rate 263 H hafnium 9 half-titanocene 12 haul off speed 132 haze 95 head-to-head insertion 101 heat of fusion 88, 261 resistance 42 transfer 54 Henrys Law 158 heterogeneous 5 HIPS 29 Hoffman-Lauritzen equation 250 homogeneous 5 hot tack 55 housing 303 hysteresis-loop 78 I immiscible 17 impact 28, 50, 89, 138 impurities 23 injection molding 41, 81 interaction 19 interpenetrating network 81 IR dichroism 113 iron 1 isomorphism 190 isostrain 117 isostress 117 isotactic 9, 101, 279 308 Metallocene TechnologyK Kaminsky 1 Kraton 29 L lamellae 23, 32, 102, 251, 257 lamellar thickness 115, 240 M markets 283 masterbatch 62 medical 93, 137, 275 melt 23, 129, 170, 177 fracture 223 index 69, 138, 204 instability 97 strength 201 temperature 62 melting 18, 190 behavior 69 instability 74 point 31, 58, 95, 102, 258 methylaluminoxane 1 microscopy 30 Mie-theory 148 military helmets 160 miscibility 27 modeling 38 modified atmosphere 86 modulus 19 molecular stiffness 272 weight 77 morphology 3, 29, 38, 41, 111, 148, 247 N nanodispersion 148 nanoscale 25 Newtonian flow 95 nickel 1 NMR 112, 231 NRA 29 nucleating agent 27, 148 nucleation 131, 158, 244, 257, 269 nuclei concentration 247 O olefins 293 operation variables 154 optical clarity 275 properties 48, 101 orientation 32, 90, 116, 177 output 62 oxygen 86 Ozawa exponent 265 P packaging 53, 85, 93, 137, 147, 275, 299 packing 167 PBT 278 permeability 85 pipe 303 plasticizer 277 platelets 23 polydispersity 1, 13, 18, 193, 232 polyethylene 17, 41, 47, 53, 62, 77, 86, 93, 111, 121, 129, 137, 153, 161, 183, 202, 209, 234, 239, 257, 277, 283, 293 polymerization 2 polymorphism 29, 167 polyolefins 9, 111, 157, 183, 258, 277 polypropylene 10, 18, 23, 77, 101, 147, 164, 167, 177, 183, 194, 263, 278, 283, 293, 299 polystyrene 29, 37, 147 pressure 50, 65 prices 295 printability 41 processability 153, 203 propylene 13 PTMO 278 pumping capacity 64 Index 309PVC 277, 303 Q quality 67 R Raman 112 refractive index 42 relaxation spectrum 193 studies 17 respiration 86 rheology 38, 62, 96 rheometer 80, 131, 169, 232 rotation 10 rubber 293 rubbery phase 114 S SAXS 112 screw 61 design 69 seal 54 sealability 41 sealing strength 91 SEBS 278 SEC 193 segregation 23, 25 SEM 158 shear rate 213 shear thinning 217 sheets 168 shrinkage 171 silica 2 SIST 103 slit-tapes 168 slurry process 47 sol-gel transition 149 solidification 38 spherulite 23, 33, 147, 247, 252, 257 spinning 168, 177 stabilization 195 stereochemistry 9, 101 stereomodifiers 147 stereoregularity 101, 188 sterilization 275 stiffness 27, 88, 150 storage 85 strain hardening 108, 235 stress analysis 178 stress-strain 78 styrene 10 supercooling 217, 251, 258 surface 67, 98 syndiotactic 12, 29, 187 T TDA 178 tear resistance 89 strength 51, 123, 138 TEM 113 tenacity 171 tensile modulus 88 strength 50, 132, 178 texture 116 T g 37, 276 thermoformability 41 tie-molecules 261 titanium 9 dioxide 62 torque 134 toughness 27, 47 TPE 276 transcrystallization 112, 118 transparent 148 triisobutylaluminium 2 tubing 97 310 Metallocene TechnologyU unsaturations 186, 195 V vinyl 186 vinylidene 186 viscoelastic studies 93 viscosity 80, 134, 139, 195, 210, 233 W WAXD 169, 178 WAXS 31, 112 wetting 54 Y yield stress 108 yielding 107 Youngs modulus 82, 117, 133 Z Ziegler-Natta 1, 17, 69 zirconium 9 Index 311
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