كتاب Metallocene Technology in Commercial Applications
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 كتاب Metallocene Technology in Commercial Applications

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Metallocene Technology inCommercial Applications
Dr. George M. Benedikt, Editor

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Table of Contents
Preface vii
George M. Benedikt
Catalytic Systems
Single-Site Supported Catalysts for Ethylene 1
A. MuÔoz-Escalona, L. Mendez, B. PeÔa, P. Lafuente, J Sancho,
W. Michiels, G. Hidalgo and Ma. Fca. Martinez-NuÔez
Synthesis of High-Molecular-Weight Elastomeric Polypropylene with
Half-Titanocene/MAO Catalysts 9
Oing Wu, Benheng Xie, Meiran Xie, Rui Chen
Precessing Methods
Blending
Is Metallocene Polyethylene Blend with HDPE More Compatible Than with PP? 17
D. Rana, K. Cho, B. H. Lee and S. Choe
Spherulite Boundary Strengthening: A New Concept in Polymer Blends 23
A. Lustiger, CN. Marzinsky and R. R. Mueller
Modification of Syndiotactic Polystyrene 29
JØrg Kressler, Ralf Thomann
Blends of Ethylene/Styrene Interpolymers and Other Polymers: Benefits in
Applications 37
C.F. Diehl, M. J. Guest, B. I. Chaudhary, Y. W. Cheung,
W. R. Van Volkenburgh, B.W. Walther
Extrusion
Easy Processing Metallocene Polyethylene 47
Ching-Tai Lue
Effect of Metallocene Polyethylene on Heat Sealing Properties of Low
Density Polyethylene Blends 53
Juan D. Sierra, Mar˝a del Pilar Noriega and Tim A. Osswald
Extrusion Operation Window for Filled Metallocene Polyethylenes 61
Mar˝a del Pilar Noriega and Tim A. Osswald, Omar A. Estrada
Processing Trends of Metallocene Linear Low Density Polyethylenes and
Their Influence on Single Screw Design 69K. R. Slusarz, C. A. Ronaghan, and J. P. Christiano
Influence of mPE Grades on the Dynamic Properties of PP/mPE-Blends 77
Frank Raue and Gottfried W. Ehrenstein
fiSingle-Site Catalyzed Polyolefin for Fresh-Cut Produce Packaging.
A Comparison Between Monoextruded Blends and Coextruded Film 85
V. Patel, S. Mehta, S. A. Orroth and S. P. McCarthy
Rheology and Processing Experience of New Metallocene Polyolefins 93
Atul Khare, Chuan Qin, Michael T. K. Ling, and L. Woo
Film Forming
Properties and Film Applications of Metallocene-Based Isotactic Polypropylenes 101
Aiko Hanyu and Rusty Wheat
Phase Structure Characterization and Processing-Structure-Property Relationships
in Linear Low-Density Polyethylene Blown Films 111
Jianjun Lu, Baiyi Zhao and Hung-Jue Sue
The Relative Influences of Process and Resin Time-Scales on the MD Tear
Strength of Polyethylene Blown Films 121
Rajendra K. Krishnaswamy and Ashish M. Sukhadia
Metallocene Catalyzed Polyethylene in Blown Film Applications. A Comparison
Between Monoextruded Blended Films and Coextruded Films 129
C. M. Beagan, G. M. Mc Nally & W. R. Murphy
Trade-offs in Blown Film Processing-Structure-Property Behavior of LLDPE
Type Resins from Chromium, Metallocene and Ziegler-Natta Catalysts 137
Ashish M. Sukhadia
Injection Molding
Transparent Metallocene-Polypropylene for Injection Molding 147
J. RØsch, J. R. Grasmeder
Equipment Design Considerations for Processing with Metallocene Resins 153
Andrew W. Christie
Other Processing Methods
Product and Process Developments in the Nitrogen Autoclave Process for
Polyolefin Foam Manufacture 157
D. E. Eaves and N. Witten
Properties of Syndiotactic Polypropylene Fibers Produced from Melt Spinning 167
Mohan Gownder
iv Metallocene TechnologyMelt Spinning of Syndiotactic Polypropylene: Structure Development and
Implications for Oriented Crystallization 177
Ravi K. Sura, Prashant Desai and A.S. Abhiraman
Properties
New Polyolefins Characterization by Instrumental Analysis 183
Carmina Gartner and Juan D. Sierra, Roger Avakian
Dynamic Melt Rheometry Used to Study Degradation of Metallocene
Polyethylene 193
Scott H. Wasserman, George N. Foster, Douglas J. Yacka
Melt Rheology and Processability of Conventional and Metallocene
Polyethylenes 201
Choon K. Chai
Rheology of Metallocene-Catalyzed Polyethylenes. The Effects of Branching 209
Sujan E. Bin Wadud and Donald G. Baird
Extensional and Shear Rheology of Metallocene-Catalyzed Polyethylenes 217
Sujan E. Bin Wadud and Donald G. Baird
A Criterion for the Onset of Gross Polyolefins: Molecular Structure Effect 223
Seungoh Kim and John. M. Dealy
Relationship Between Structure and Rheology of Constrained Geometry
Catalyzed and Metallocene Polyethylenes 231
Paula Wood-Adams and John M. Dealy
The Influence of Sequence Length Distribution on the Linear Crystal Growth
of Ethylene-Octene Copolymers 239
John E. Wagner, Samir Abu-Iqyas, Kenneth Monar and Paul J. Phillips
Crystallization and Microstructure of Ziegler-Natta and Metallocene Based
Isotactic Polypropylenes: Simulation and Experiment 247
Y. Churdpunt and A. I. Isayev
Crystallization of Ethylene-Octene Copolymers at High Cooling Rates 257
Paul J. Phillips and John Wagner
Kinetics of Non-Isothermal Crystallization Syndiotactic Polypropylene:
Avrami, Ozawa, and Kissinger Approaches 263
Pitt Supaphol and Joseph E. Spruiell
High Temperature Flexible Polyolefins a User™s Perspective 275
Atul Khare, Samuel Y Ding, Michael T. K. Ling, and L. Woo
Table of Contents vMarkets
An Outlook for Metallocene and Single Site Catalyst Technology into
the 21st Century 283
Kurt W. Swogger
World Olefins Markets: Issues Influencing Availability and Pricing 293
Robin G. Harvan
World Polypropylene Demand 299
Russ DeLuca
PVC Markets, Today and in 2020 303
Donald Goodman
Index 307
vi Metallocene TechnologyPrefac
A
ABS 293
activation energy 29, 97, 212, 271
agricultural films 137
amorphous 9, 23, 37, 112, 147
agent 130
appearance 67
atactic 9, 23, 29, 37, 187, 279
autoclaving 275
Avrami
equation 249
kinetics 263
theory 157, 265
B
bags 137
barrel 73
birefringence 178, 223
birefringent 148
blends 17, 27, 29, 38, 48, 53, 62, 77, 129, 164
blow molding 87, 117, 122
blowing agent 157
branches 5, 261
branching 193, 217, 232
brittleness 29
bubble 118, 122
stability 204
C
can liners 137
capillary flow 223
cell structure 159
chain 13
chromium 1
clarity 47, 147
cobalt 1
coextrusion 129
compatibility 17
conductivity 165
conformation 167, 180, 279
contamination 275
cooling 247
copolymers 6, 31, 164, 194, 209, 258
distribution 77
copolymerization 10, 239
Cox-Merz rule 234
CP/MAS 178
critical stress 227
crosslinking 157, 193
crystalline 23
modifications 29
crystallinity 94, 107, 264
crystallites 105
crystallization 18, 54, 112, 117, 150, 177, 239,
257, 263
kinetics 168
cushioning 160
cyclic loading 78
D
damping factor 78
debonding 38
defects 102
degradation 194
die 64, 224
diffusion 54, 159
DMS 178
Doi-Edwards model 233
driving force 13
IndexDSC 15, 26, 30, 55, 87, 103, 113, 130, 135, 170,
178, 183, 248, 252, 264, 266
dynamic modulus 82
E
elastic recovery 172
elasticity 41
elongation 20, 132, 171
endotherm 106
EPDM 77, 279
EPR 279
equipment design 154
ethylene 1
ethylene/styrene interpolymer 37
EVA 53, 86, 94, 163, 278
exotherm 267, 272
expansion 157
extensional
flow 224
viscosity 217
extractables 148
extruder 48, 61, 138, 154, 177
extrusion 17, 69, 86, 97, 170, 197, 201, 223
F
fatigue 78
fiber 168, 177
film 17, 38, 69, 85, 111, 117, 122, 129, 168, 177,
201
flexural modulus 27
Flory equation 240, 258
foam 38, 157
fold surface 261
food 93, 137
free energy 261
fresh-cut produce 85
FTIR 183
microscopy 26
fusion 189
G
gas permeability 47
gelation 150
GPC 6, 18, 236
growth rate 263
H
hafnium 9
half-titanocene 12
haul off speed 132
haze 95
head-to-head insertion 101
heat
of fusion 88, 261
resistance 42
transfer 54
Henry™s Law 158
heterogeneous 5
HIPS 29
Hoffman-Lauritzen equation 250
homogeneous 5
hot tack 55
housing 303
hysteresis-loop 78
I
immiscible 17
impact 28, 50, 89, 138
impurities 23
injection molding 41, 81
interaction 19
interpenetrating network 81
IR dichroism 113
iron 1
isomorphism 190
isostrain 117
isostress 117
isotactic 9, 101, 279
308 Metallocene TechnologyK
Kaminsky 1
Kraton 29
L
lamellae 23, 32, 102, 251, 257
lamellar thickness 115, 240
M
markets 283
masterbatch 62
medical 93, 137, 275
melt 23, 129, 170, 177
fracture 223
index 69, 138, 204
instability 97
strength 201
temperature 62
melting 18, 190
behavior 69
instability 74
point 31, 58, 95, 102, 258
methylaluminoxane 1
microscopy 30
Mie-theory 148
military helmets 160
miscibility 27
modeling 38
modified atmosphere 86
modulus 19
molecular
stiffness 272
weight 77
morphology 3, 29, 38, 41, 111, 148, 247
N
nanodispersion 148
nanoscale 25
Newtonian flow 95
nickel 1
NMR 112, 231
NRA 29
nucleating agent 27, 148
nucleation 131, 158, 244, 257, 269
nuclei concentration 247
O
olefins 293
operation variables 154
optical
clarity 275
properties 48, 101
orientation 32, 90, 116, 177
output 62
oxygen 86
Ozawa exponent 265
P
packaging 53, 85, 93, 137, 147, 275, 299
packing 167
PBT 278
permeability 85
pipe 303
plasticizer 277
platelets 23
polydispersity 1, 13, 18, 193, 232
polyethylene 17, 41, 47, 53, 62, 77, 86, 93, 111,
121, 129, 137, 153, 161, 183, 202, 209, 234,
239, 257, 277, 283, 293
polymerization 2
polymorphism 29, 167
polyolefins 9, 111, 157, 183, 258, 277
polypropylene 10, 18, 23, 77, 101, 147, 164,
167, 177, 183, 194, 263, 278, 283, 293, 299
polystyrene 29, 37, 147
pressure 50, 65
prices 295
printability 41
processability 153, 203
propylene 13
PTMO 278
pumping capacity 64
Index 309PVC 277, 303
Q
quality 67
R
Raman 112
refractive index 42
relaxation
spectrum 193
studies 17
respiration 86
rheology 38, 62, 96
rheometer 80, 131, 169, 232
rotation 10
rubber 293
rubbery phase 114
S
SAXS 112
screw 61
design 69
seal 54
sealability 41
sealing strength 91
SEBS 278
SEC 193
segregation 23, 25
SEM 158
shear rate 213
shear thinning 217
sheets 168
shrinkage 171
silica 2
SIST 103
slit-tapes 168
slurry process 47
sol-gel transition 149
solidification 38
spherulite 23, 33, 147, 247, 252, 257
spinning 168, 177
stabilization 195
stereochemistry 9, 101
stereomodifiers 147
stereoregularity 101, 188
sterilization 275
stiffness 27, 88, 150
storage 85
strain hardening 108, 235
stress analysis 178
stress-strain 78
styrene 10
supercooling 217, 251, 258
surface 67, 98
syndiotactic 12, 29, 187
T
TDA 178
tear
resistance 89
strength 51, 123, 138
TEM 113
tenacity 171
tensile
modulus 88
strength 50, 132, 178
texture 116
T
g 37, 276
thermoformability 41
tie-molecules 261
titanium 9
dioxide 62
torque 134
toughness 27, 47
TPE 276
transcrystallization 112, 118
transparent 148
triisobutylaluminium 2
tubing 97
310 Metallocene TechnologyU
unsaturations 186, 195
V
vinyl 186
vinylidene 186
viscoelastic studies 93
viscosity 80, 134, 139, 195, 210, 233
W
WAXD 169, 178
WAXS 31, 112
wetting 54
Y
yield stress 108
yielding 107
Young™s modulus 82, 117, 133
Z
Ziegler-Natta 1, 17, 69
zirconium 9
Index 311


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